BHA Butylated Hydroxyanisole Manufacturers, MSDS Sheet
Mubychem Limited of USA & India is a pioneer manufacturers suppliers exporters & importers of chemicals including Hydraulic fracturing stimulation & oil well production chemicals, Pharmaceutical excipients, Fragrance & flavor chemicals. Muby Chem Ltd has several manufacturing facilities and toll manufacturers across the globe. We have offices warehouses and representatives in Houston & Midland Texas and Chicago Illinois USA. Our suppliers have accreditations like FDA - GMP-GLP approval, ISO-9001, ISO-22000 HACCP, Kosher & Halal Certification. We offer Commercial Pure Pharmacopoeia Analytical Reagent & Food Grade of Chemicals and do Toll Manufacturing for Oil well drilling fracking fracturing and others. Apart from Butylated hydroxyanisole Manufacturers we also manufacture Butylated hydroxytoluene, and Tertiary or Tert Butylhydroquinone the main antioxidants for oils and fats.
Typical Analysis & Butylated hydroxyanisole specifications:
Butylated hydroxyanisole is a white to slightly yellow waxy flakes with characteristic odor.
It is freely soluble in alcohol, propylene glycol. It is insoluble in water.Test ---------------- Result - Specification
Melting Point ------- 62.6C -- 48C to 63C
Residue on ignition - 0.018% - 0.05% max
Arsenic ------------- <1ppm -- 3ppm max
Assay --------------- 99.06% - 98.5% min of C11H16O2Packing will be 25-50 kg or 50 lbs in bags or drums or as desired by the buyer.
Salient Features of BHAThe most effective antioxidant, imparting excellent stability for an array of food products, fats, shortenings, vitamins, pet foods, cosmetics pharmaceutical products and packaging material.
BHA, reduces the oxidative deterioration of edible oils and fats, loss of flavor, colour and nutritive value of foods.
BHA, THE BETTER ANTIOXIDANT : BHA normally is a mixture of 2 isomers, 2 tert butyl and 3 tert butyl isomers 3 tert butyl isomer has better antioxidant property.
White free flowing crystalline Flakes.
Stable to heat and mildly alkaline conditions.
20% colorless solution in propylene glycol remains colorless even when heated at 1940F for 1hr.
BHA SYNERGISTIC EFFECT : BHA gives greater synergistic effect with TBHQ, BHT and propyl gallate than that which might be expected from contribution of each individual antioxidant.
BHA Butylated Hydroxyanisole SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
CAS No.: 25013-16-5
Molecular Weight: 180.25
Chemical Formula: C11H16O22. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008Acute toxicity, oral (Category 4)
Skin irritation (Category 2)
Eye irritation (Category 2A)
Carcinogenicity (Category 2)
Specific target organ toxicity - single exposure (Category 3), Respiratory systemLabeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
IrritantGHS Label Elements
Health HazardSignal Words: Warning
Hazard statements:
H302: Harmful if swallowed.
H315: Causes Skin Irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation
H351: Suspected of causing cancer.Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.
P314: Get medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.3. Composition/Information on Ingredients
Ingredient: Butylated Hydroxyanisole, BHA
CAS No.: 25013-16-5
Percent: 97 - 100%4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting Measures
Flammability of the Product: May be combustible at high temperature..
Flash Points: 156C.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Fire: Flammable in the presence of open flame.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. Containers may explode on heating6. Accidental Release Measures
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.7. Handling and Storage
Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Not established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Appearance: Butylated Hydroxyanisole, BHA is a white to off-white waxy solid.
Odor: It has faint typical odor.
Solubility: It is immiscible in water.
pH: NA
Density: 1.05 g/mL at 20C (68F)
Molecular Weight: 180.2
Molecular Formula: C11H16O2
% Volatiles by volume @ 21C (70F): -
Boiling Point: 264-270°C
Melting Point: 48 - 55 deg C10. Stability and Reactivity
Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, reducing agents metals and acids.
Conditions to Avoid: Incompatibles and moisture.
Phenols are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides.
Avoid use of aluminum, copper and brass alloys in storage and process equipment.
Heat is generated by the acid-base reaction between phenols and bases.
Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature), these reactions generate heat.
Phenols are nitrated very rapidly, even by dilute nitric acid.
Nitrated phenols often explode when heated. Many of them form metal salts that tend toward detonation by rather mild shock.
Segregate from oleum, nitric acid and chlorosulfonic acid.11. Toxicological Information
Toxicity data
ORL-RAT LD50 > 2000 mg kg-1
ORL-MAM LD50 1100 mg kg-1
Carcinogenic Effects: Classified 2B (Possible for human.) by IARC. Classified 2 (Some evidence.) by NTP.
Mutagenic Effects: Mutagenic for bacteria and/or yeast.
Teratogenic Effects: Teratogenic effects have occurred in experimental animals.
Developmental Toxicity: Adverse reproductive effects have occurred in experimental animals.12. Ecological Information
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
US DOT & ADR/RID Classification: Not Regulated
Canada TDG Classification: Not Regulated
IATA: Not Regulated15. Regulatory Information
USA:
SARA 302 Components : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: No chemicals are reportable under Section 313.
SARA 311/312 Hazards
Component CAS # 25013-16-5.
Fire Hazard: No; Reactivity Hazard: No; Pressure Hazard: No; Immediate Health Hazard: Acute
Chronic Health Hazard: Delayed.Canada - DSL/NDSL: CAS# 7447-39-4 is listed on Canada's DSL List.
Canada - WHMIS: CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
Canadian Ingredient Disclosure List: CAS# 25013-16-5 is listed on the Canadian Ingredient Disclosure List.Section 16 - Additional Information
Disclaimer:
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Our company provides this BHA Butylated Hydroxyanisole SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Butylated Hydroxyanisole, BHA MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
**************************BHA Butylated Hydroxyanisole manufacturers:
Muby Chem Ltd.
Toll manufacturing & Warehouse at Houston & Midland, Texas, USA and India
USA, Canada, Mexico Customers may e-mail: usa@mubygroup.com
Call 1-844-682-9243Europe Africa Asia India Mumbai e-mail: info@mubygroup.com
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