Sodium Sulfide Nonahydrate SDS MSDS of Suppliers & Manufacturers

Mubychem Limited of USA & India is a pioneer manufacturers suppliers exporters & importers of chemicals including Hydraulic fracturing stimulation & oil well production chemicals, Pharmaceutical excipients, Fragrance & flavor chemicals. Muby Chem Ltd has several manufacturing facilities and toll manufacturers across the globe. We have offices warehouses and representatives in Houston & Midland Texas and Chicago Illinois USA.

Our suppliers have accreditations like FDA - GMP-GLP approval, ISO-9001, ISO-22000 HACCP, Kosher & Halal Certification. We offer Commercial Pure Pharmacopoeia Analytical Reagent & Food Grade of Chemicals and do Toll Manufacturing for Oil well drilling fracking fracturing and others.

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Sodium Sulfide Nonahydrate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 23-Dec-21

Product Name & Other Names: Sodium Sulfide Nonahydrate or Sodium monosulfide nonahydrate or Sodium sulphide nonahydrate.
CAS No.: 1313-84-4
EINECS EC-No.: 215-211-5

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4) H302
Acute toxicity, Dermal (Category 3) H311
Skin corrosion (Category 1B) H314
Acute aquatic toxicity (Category 1) H400

Hazard statements:
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H400: Very toxic to aquatic life.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P333+313: If skin irritation or a rash occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.

Product Name & Other Names: Sodium Sulfide Nonahydrate or Sodium monosulfide nonahydrate or Sodium sulphide nonahydrate.
CAS No.: 1313-84-4
EINECS EC-No.: 215-211-5

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Non-flammable.
Products of Combustion: Sulphur oxides, Sodium oxides, fumes.
Fire: Sodium Sulfide Nonahydrate is not considered to be a fire hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use water to cool fire-exposed containers.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Corrosive solid. Avoid touching the spilled material. Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Do not ingest. Do not breathe dust. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like strong oxidizing agents, metals, acids.

Airborne Exposure Limits: Not established for the product. However, if Hydrogen sulfide is released in handling and use, then observe its limits.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area.

Appearance: Yellowish powder.
Odor: rotten egg-like.
Odor threshold: Not available.
pH: Alkaline
Relative density: around 1.43
Boiling Point: 920C - lit.
Melting Point: 50C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It soluble in water.
Viscosity: Not available.

Stability: Stable under ordinary conditions of use and storage. One can say it is moderately stable in atmospheric condition. Aqueous solutions and moist solid may slowly give off hydrogen sulfide gas. Air and light sensitive. May discolor on exposure to air. Liberates toxic hydrogen sulfide on contact with acids. Reacts violently with carbon, diazonium salts; n,n-dichloromethylamine, o-Nitroaniline, diazonium salt, water. Reacts with water to form strong solutions and Hydrogen sulfide Reacts with acid more vigorously , producing corrosive solutions, and hydrogen sulfide. Also incompatible with Acids, Aluminum, Zinc. Decomposes in air at 920-950 deg. C.
Hazardous Decomposition Products: It emits toxic hydrogen sulfide fumes when heated to decomposition. It may form sodium oxide and sulfur.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, metals & acids.
Conditions to Avoid: Incompatibles and moisture.

Toxicity data
Oral LD50 Mouse: 205 mg/kg
Oral LD50 Rat: 208 mg/kg; Intraperitoneal LD50 147 mg/kg
LD50 Dermal: < 340 mg/kg ( Rabbit )
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

Toxicity to fish: LC50: 7.7 - 29.1 mg/L, 96h (Poecilia reticulata) for Na2S
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

DOT USA, TDG Canada & ADR/RID Europe:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED
IMDG/IMO:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED
IATA:
UN number: 1849 Class: 8 Packing group: II
Proper shipping name: SODIUM SULFIDE, HYDRATED

USA:
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Muby Chem Ltd.
Toll manufacturing & Warehouse at Houston & Midland, Texas, USA and India
USA, Canada, Mexico Customers may e-mail: usa@mubygroup.com
Call 1-844-682-9243

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