Titanium Dioxide Manufacturers, SDS MSDS Sheet

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Titanium Dioxide USP BP IP FCC Food grade Manufacturers

Titanium Dioxide
Technical & Pure
Also IP BP Ph. Eur. USP ACS AR LR FCC Food Grades

Titanium Dioxide

Titanium Dioxide SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Titanium (IV) Oxide; C.I. 77891; Titania
CAS No.: 13463-67-7
Molecular Weight: 79.87
Chemical Formula: TiO2

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
NONE

Signal Word: None

Hazards not otherwise classified (HNOC):
May causes mild skin irritation.
May causes mild eye irritation.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

3. Composition/Information on Ingredients

Ingredient: Titanium Dioxide
CAS No.: 13463-67-7

4. First Aid Measures

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Not expected to require first aid measures. If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard.
Fire Extinguishing Media: It is neither flammable nor explosive. Titanium dioxide may be exposed to water, carbon dioxide, dry chemical, and foam extinguishing agents as necessary during fire fighting operations.

6. Accidental Release Measures

A spill of titanium dioxide poses hazards similar to other nuisance dusts. Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions, provide adequate ventilation.

7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Respiratory Protection: Use NIOSH approved respirator when use is necessary. As with any nuisance dust, the use of NIOSH approved respirators is recommended in cases where prolonged exposure is expected.
Skin Protection: Wear appropriate protective gloves and clothing to prevent skin exposure.
Eye Protection: Wear appropriate protective glasses or chemical safety goggles.
Other Protective Equipment: Wear appropriate protective clothing to minimize contact with skin.
Titanium dioxide can adsorb moisture and natural oils from the surface of the skin during prolonged exposure. Prolonged exposure should be avoided by wearing suitable protective gloves and clothing.

9. Physical and Chemical Properties

Appearance: White powder.
Odor: Odorless.
Solubility: Insoluble in water.
Specific Gravity: 4.26
pH: 6 - 7
% Volatile by volume @ 21C (70F): 0
Boiling Point: 2500 - 3000C (4532 - 5432F)
Melting Point: 1855C (3371F)

10. Stability and Reactivity

Stability:  It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: No information found.
Hazardous Polymerization: Will not occur.
Incompatibilities: A violent reaction with lithium occurs around 200C (392F) with a flash of light; the temperature can reach 900C. Violent or incandescent reaction may also occur with other metals such as aluminum, calcium, magnesium, potassium, sodium, and zinc.

11. Toxicological Information

Toxicological Data:
LD50/rat: > 5,000 mg/kg
Carcinogenicity:
NIOSH considers this substance to be a potential occupational carcinogen.
--------\Cancer Lists\--------------
---------------- ---NTP Carcinogen--
Ingredient ----- - Known - Anticipated - IARC Category
Titanium Dioxide - Yes ----- Yes ---------- 3
(13463-67-7)

12. Ecological Information

Toxicity to fish: LC50/96 h/Pimephales promelas (fathead minnow): > 1,000 mg/l
Acute toxicity to aquatic invertebrates: EC50/LC50 = 1000 mg/L 72 hour
Environmental Fate: No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with legal requirements.

14. Transport Information

DOT (US): Not dangerous goods
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods

15. Regulatory Information

USA Regulations:
SARA 311/312: Acute: Yes; Chronic: Yes; Fire: No; Pressure: No; Reactivity: No (Pure / Solid).

16. Other Information

Disclaimer:
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Our company provides this Titanium dioxide SDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This Titanium dioxide MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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