Glycerol Formal SDS MSDS of Suppliers Exporters, CAS 99569-11-6

Muby Group of USA & India is a pioneer manufacturers suppliers exporters & importers of chemicals including Glycerol Formal BP Ph Eur Grade, Hydraulic fracturing stimulation & oil well production chemicals, Pharmaceutical excipients and API, Fragrance & flavor chemicals. Muby Group has several manufacturing facilities and toll manufacturers across the globe. We have offices warehouses and representatives in Houston & Midland Texas and Chicago Illinois USA.
Our suppliers have accreditations like FDA - GMP-GLP approval, ISO-9001, ISO-22000 HACCP, Kosher & Halal Certification. We offer Commercial Pure Pharmacopoeia API Excipients Analytical Reagent & Food Grade of Chemicals and do Toll Manufacturing for Oil well drilling fracking fracturing and others.

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Glycerol Formal BP Ph Eur Grade Manufacturers

Glycerol Formal SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Product Name & Other Names: Glycerol Formal.
CAS Number: 99569-11-6 or 4740-78-7
EINECS EC Number: 226-758-4 or 225-248-9
Molecular Weight: 104.10
Chemical Formula: C4H8O3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Eye irritation, Category 2, H319
Reproductive toxicity Category 2, H361

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant		 GHS Label Elements
Health Hazard
Health Hazard

Signal Words: Warning

Hazard Statements:
H319: Causes serious eye irritation.
H361: Suspected of damaging fertility or the unborn child.

Precautionary Statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash contaminated parts thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P302+352: IF ON SKIN: Wash with plenty of soap and water.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P403 P404: Store in well-ventilated place. Keep container tightly closed.
P501: Dispose of contents/container in accordance with local/national regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
Xn Harmful.
Xi Irritant.
Risk Phrases:
R36 Irritating to eyes.
R60 May impair fertility.
R61 May cause harm to the unborn child.

3. Composition/Information on Ingredients

Product Name & Other Names: Glycerol Formal.
CAS Number: 99569-11-6 or 4740-78-7
EINECS EC Number: 226-758-4 or 225-248-9

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove affected person to fresh air; if normal breathing has not returned within a few minutes after exposure, get medical attention.
Skin: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse. Seek medical attention.
Eyes: Immediately, flush eyes for 15 minutes in clear running water while holding eyelids open; seek medical attention immediately.
Ingestion: Drink two glasses of water followed by milk, milk of magnesia or other non-alcoholic liquids; Do not induce vomiting; seek medical attention immediately.
Physician may treat symptomatically.

5. Fire Fighting Measures

Flash Point: 93C
General Hazards: Contact with eyes causes immediate severe irritation of the eye and eyelids. Product will support combustion.
Extinguishing Media: Carbon dioxide, water fog, dry chemical, chemical foam. Keep containers cool by spraying with water. Use extinguishing media appropriate for surrounding fire.
Fire & Explosion Hazard: May evolve oxides of carbon (COx) and fumes under fire conditions.
In case of fire, wear a full face positive-pressure self-contained breathing apparatus and protective suit. Self - contained respiratory equipment; cool containers to prevent pressure buildup and possible explosion when exposed to extreme heat. Caution - material will support combustion!
Unusual Fire and Explosion Hazards: Closed containers can explode due to buildup of pressure when exposed to extreme heat.
Hazardous Combustion Products: Products of combustion include CO, CO2 and toxic fumes.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and a suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter sewer, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Vacuum or sweep up and remove to an approved disposal container.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids. Keep containers closed when not in use; protect containers from abuse; protect from extreme temperatures, open flames. Avoid contact with water or humidity. This material will support combustion. Keep this and other chemicals out of reach of children.

8. Exposure Controls/Personal Protection

Engineering Controls: The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation of confined spaces. Use corrosion-resistant, explosion-proof ventilation equipment.
Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Colorless liquid.
Odor: Characteristic.
Odor threshold: Not available.
pH: 4.0 to 6.5.
Relative density: 1.210 to 1.220.
Melting point/freezing point: Not available.
Boiling Point: 192C to 193C literature.
Flash point: 93C.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Pressure (MM Hg): Not available.
Vapor Density (Air = 1): Not available.
Evaporation Rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility in Water: Miscible with water and ethanol.
Viscosity: Not available.

10. Stability and Reactivity

Stability: Stable at normal temperatures and operating conditions. Forms explosive mixtures with air on intense heating.
Conditions to Avoid: Avoid excessively high temperatures, sunlight, air, moisture, and incompatibles.
Incompatibilities: Strong oxidizing agents, Strong acids.
Decomposition: Decomposition yields carbon monoxide & dioxide, fumes.
Polymerization: Polymerization will not occur.

11. Toxicological Information

Reproduction: Possible risk of harm to the unborn child.
Mutagenicity: Not available.
Carcinogenicity: Not listed as a human carcinogen by OSHA, IARC, ACGIH & NTP.
Acute Oral Effects: Oral LD50 – Rats >2000 mg/kg.
Acute Dermal Toxicity: LD50 Dermal - Rat >2000 mg/kg.

12. Ecological Information

Toxicity to fresh-water fish: Not available.
Persistence and accumulation: Accumulation is unlikely.
Mobility: Will likely be mobile in the environment due to its water solubility.

13. Disposal Considerations

Dispose in accordance with Local, State, and Federal Regulations. Consult local, state, or Federal Environmental Protection Agency before disposing of any chemicals. Follow all the pollution control rules.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG/IMO & IATA/ICAO: Not dangerous goods.

15. Regulatory Information

UNITED STATES REGULATORY INFORMATION
SARA 311/312 Hazard Categories: See section 2.

Section 16 - Additional Information

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Glycerol Formal BP Ph Eur Grade Manufacturers:

Glycerol Formal Manufacturers

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11 October, 2026