Formaldehyde Solution SDS MSDS of Suppliers & Manufacturers

Mubychem Limited of USA & India is a pioneer manufacturers suppliers exporters & importers of chemicals including Hydraulic fracturing stimulation & oil well production chemicals, Pharmaceutical excipients, Fragrance & flavor chemicals. Muby Chem Ltd has several manufacturing facilities and toll manufacturers across the globe. We have offices warehouses and representatives in Houston & Midland Texas and Chicago Illinois USA.

Our suppliers have accreditations like FDA - GMP-GLP approval, ISO-9001, ISO-22000 HACCP, Kosher & Halal Certification. We offer Commercial Pure Pharmacopoeia Analytical Reagent & Food Grade of Chemicals and do Toll Manufacturing for Oil well drilling fracking fracturing and others.

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Formaldehyde Solution (with Methanol) SDS Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 20-Dec-21

Product Name & Other Names: Formalin (with Methanol)
CAS No.: 50-00-0
EINECS EC Code: 200-001-8

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 3), H301
Acute toxicity, Dermal (Category 3), H311
Acute toxicity, Inhalation (Category 3), H331
Skin corrosion (Category 1B), H314
Skin sensitization (Category 1), H317
Germ cell mutagenicity (Category 2), H341
Carcinogenicity (Category 1B), H350
Specific target organ toxicity - single exposure (Category 1), H370
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335

Hazard Statements:
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H370 Causes damage to organs.

Precautionary Statements
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P363: Wash contaminated clothing before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.

Ingredient I: Formaldehyde 30-45% in water.
CAS No.: 50-00-0
EINECS EC Code: 200-001-8
Ingredient II: Methanol 5-20% in water.
CAS No.: 67-56-1
EINECS EC Code: 200-659-6

Inhalation: Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Contact medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.

Fire: Flash point: Not available.
Toxic fumes, carbon dioxide and carbon monoxide may be formed in fire.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide and water spray jet.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Mop and pick up the material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Absorb with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep up and remove to an approved disposal container. Avoid mist formation. Keep away from heat. Keep away from sources of ignition. Provide ventilation. Contact Environment Agency.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc).
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like strong oxidizing agents, aniline, phenol, isocyanates, acid anhydrides, strong acids, strong bases, amines, peroxides, acid chlorides, alkali metals, reducing agents. Do not breathe mist or dust. Containers of may be hazardous when empty. Avoid contact.

Airborne Exposure Limits:
Formaldehyde 37%, in Aqueous Solution
ACGIH: TLV-C 0.3 ppm
USA OSHA: PEL (TWA) 0.75 ppm
USA OSHA: PEL (STEL) 2 ppm
USA IDLH: 20 ppm
Methanol
ACGIH: TLV-TWA 200 ppm
ACGIH TLV-STEL: 250 ppm
USA OSHA: PEL (TWA) 260 mg/m³
USA OSHA: PEL (TWA) 200 ppm.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, aniline, phenol, isocyanates, acid anhydrides, strong acids, strong bases, amines, peroxides, acid chlorides, alkali metals, reducing agents.

Appearance: Clear liquid.
Odor: Typical aldehyde pungent smell.
Odor threshold: Not available.
pH: Not available.
Relative density: around 1.09
Boiling Point: >100C
Melting Point: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: miscible with water
Viscosity: Not available.

Stability: Stable under ordinary conditions of use and storage with the stabilizer.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide and toxic fumes may form when heated to decomposition.
Incompatibilities: Strong oxidizing agents, Aniline, Phenol, Isocyanates, Acid anhydrides, Strong acids, Strong bases, Amines, Peroxides, Acid chlorides, Alkali metals, Reducing agents, heat and sparks.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

Oral rat LD50: Not available
The product is listed as carcinogen, Group 1: Carcinogenic to humans (Formaldehyde).
Warning: contains methanol. May be fatal or cause blindness if swallowed.
Mutagenic Effects: Not available.
Reproductive Effects: No information available.

Environmental Toxicity: Toxic to fish and aquatic life.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

DOT USA, TDG Canada & ADR/RID Europe
UN Number: 2209, Class: 8, Packing group: III
Proper shipping name: Formaldehyde solution
IMDG & IATA
UN Number: 2209, Class: 8, Packing group: III
Proper shipping name: Formaldehyde solution.

DISCLAIMER
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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