Copper Cupric Chloride Anhydrous Manufacturers, SDS MSDS Sheet
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Cupric Chloride Dihydrate MSDSCopper or Cupric Chloride Anhydrous SDS MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Synonyms: Coppertrace; Copper (2+) chloride anhydrous
CAS No.: 7447-39-4
Molecular Weight: 134.45
Chemical Formula: CuCl22. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Signal Words: Warning
Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H400: Very toxic to aquatic life.
H411: Toxic to aquatic life with long lasting effects.Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P501: Dispose of contents/ container to an approved waste disposal plant.OSHA Hazards: Hazardous. Harmful by ingestion., Irritant.
Emergency Overview
This is a hygroscopic material. It may cause allergic skin reaction. Inhalation of fumes may cause fever.
Causes eye and skin burns. May cause severe respiratory tract irritation with possible burns. May cause severe digestive tract irritation with possible burns.
Potential Health Effects
Eye: Causes eye burns. Exposure to particulates or solution may cause conjunctivitis, ulceration, and corneal abnormalities. May cause redness, pain, and blurred vision. Splashes from solutions may cause eye damageSkin: May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color. Symptoms include redness and Pain.
Ingestion: May cause severe damage to the digestive tract. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. May cause systemic effects. Get medical attention immediately.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.May cause ulceration and perforation of the nasal septum if inhaled in excessive quantities. Causes chemical burns to the respiratory tract.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Repeated skin contact of Cupric Chloride can cause varying degrees of problems ranging from dermatitis to ulcerations. Repeated Inhalation can cause copper to accumulates in various tissues and may result in liver, kidney, and brain damage.
3. Composition/Information on Ingredients
Ingredient: Cupric Chloride
CAS No.: 7447-39-4
Percent: 97 - 100%4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting Measures
Flammability of the Product: Non-flammable.
Products of Combustion: Not available.
Fire: Copper Chloride is not considered to be a fire hazard.
Explosion: Copper Chloride is Slightly explosive in presence of heat & Metals.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures o.r when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit hydrogen chloride. Containers may explode on heating6. Accidental Release Measures
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Cupric chloride is a corossive solid. Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.7. Handling and Storage
Toxic! Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Copper Chloride in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Permissible 1 mg/m3 TWA (dust and mist, as Cu, except copper fume) (listed under Copper compounds, n.o.s.).100 mg/m3 IDLH (dust and mist, as Cu) (listed under Copper compounds, n.o.s.).
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Appearance: Cupric Chloride is fine brown powder or crystals.
Odor: It is odorless.
Solubility: It is soluble in water.
pH: 3.
Density: 3.38 g/mL at 20C (68F)
Molecular formula: CuCl2
Molecular weight: 134.45
% Volatiles by volume @ 21C (70F): -
Boiling Point: 993C
Melting Point: 620C (Variously reported in literature)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.10. Stability and Reactivity
Stability: Hygroasopic. Cupric Chloride is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic chlorine or hydrogen chloride fumes when heated to decomposition. It may form cupric oxide and hydrogen chloride and chlorine.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, metals & acids. Also incompatible with potassium, sodium, hydrazine, nitromethane, acetylene, sodium hypobromite.
Conditions to Avoid: Incompatibles and moisture.11. Toxicological Information
Acute toxicity
Toxic if swallowed. Chronic exposure may cause damage to a variety of body organs. Harmful if inhaled.Toxicity data
CAS# 7447-39-4
Oral, mouse: LD50 = 233 mg/kg;
Oral, rat: LD50 = 584 mg/kg;
Oral, rat: LD50 = 140 mg/kg;Carcinogenic Effects: Not known to be a carcinogen.
Mutagenic Effects: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: kidneys, lungs, liver, skin.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
The substance may be toxic to heart. Repeated or prolonged exposure to the substance can produce target organs damage.12. Ecological Information
Environmental Fate: Not available.
Environmental Toxicity: It is also toxic to fish. Harmful to aquatic life in very low concentrations. Copper Chloride Anhydrous is toxic to fish and marine organisms when applied to streams, rivers, ponds or lakes.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
14. Transport Information
US DOT Classification:
UN-Number: UN 2802
Shipping Name: Copper Chloride
CLASS 8
Packing group: III
Identification: 8(Corrosive)Canada TDG Classification:
UN-Number: UN 2802
Shipping Name: Copper Chloride
CLASS 8
Packing group: III
Identification: 8(Corrosive)IATA
UN-Number: UN 2802
Shipping Name: Copper Chloride
CLASS 8
Packing group: III
Identification: 8(Corrosive)IMDG
UN number: 2802
Class: 8
Packing group: III
EMS-No: F-A, S-B
Proper shipping name: COPPER CHLORIDE
Marine pollutant: Marine pollutant15. Regulatory Information
OSHA Hazards
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA Codes
CAS # 7447-39-4: immediate, delayed.
SARA 313 Components
This material contains Cupric chloride (Copper compounds), (CAS# 7447-39-4) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
SARA 311/312 Hazards
Component CAS # 7447-39-4
Fire Hazard: No
Reactivity Hazard: No
Pressure Hazard: No
Immediate Health Hazard: Yes
Chronic Health Hazard: Yes
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
Copper Chloride Anhydrous (CAS # 7447-39-4) is listed as a Priority and Toxic Pollutant under the Clean Water Act.
CAS# 7447-39-4 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA. CAS# 7447-39-4is listed as a Toxic Pollutant under the Clean Water Act. CAS# 7447-39-4 is listed as a Toxic Pollutant under the Clean Water Act.Canada - DSL/NDSL
CAS# 7447-39-4 is listed on Canada's DSL List.
Canada - WHMIS
CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).
CLASS E: Corrosive solid.
Canadian Ingredient Disclosure List
CAS# 7447-39-4 is listed on Canada's DSL List.16. Other Information
Disclaimer:
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Our company provides this Cupric Chloride Anhydrous SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Cupric Chloride Anhydrous MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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