Ammonium Chloride SDS MSDS Sheet, IP BP USP ACS Analytical reagent FCC Food Pharma Grade Manufacturers

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Ammonium Chloride
Technical & Pure Crystals, Tablets, Blocks, Bricks Pellets
Also IP BP Ph. Eur. USP ACS AR LR FCC Food Grades

Product & Synonyms: Ammonium Chloride Sal ammoniac; Ammonium muriate, Salamaka, Salmiac, Muriate of Ammonia
CAS No.: 12125-02-9
Molecular Weight: 53.49
Chemical Formula: NH4Cl

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, Oral (Category 4), H302
Eye irritation (Category 2A), H319
Hazardous to the aquatic environment, acute hazard Category 3

Hazard statements:
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H402: Harmful to aquatic life.

Precautionary statements:
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get Medical advice/attention if you feel unwell.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P330: Rinse mouth.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P501 Dispose of contents/ container to an approved waste disposal plant.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

Fire: Ammonium Chloride is not considered to be a fire hazard. At fire temperatures ammonium chloride begins to corrode metals and may dissociate into ammonia and hydrogen chloride. Mixtures of about 16% to 25% (by volume) ammonia gas in air are flammable.
Explosion: It is not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Keep in a tightly closed container. Protect it from physical damage. Store it in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Containers of material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

Airborne Exposure Limits: Ammonium chloride:
-ACGIH Threshold Limit Value (TLV): 10 mg/m3 (TWA); 20 mg/m3 (STEL) Fume
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest.. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

pH of Ammonium Chloride : 5.5 (1% aq.sol.); 5.1 (3% aq.sol.); 5.0 (10% aq.sol.)
% Volatiles by volume @ 21C (70F): 0
Boiling Point: 520C (968F)
Melting Point: 338C (640F) Sublimes
Vapor Density (Air=1): 1.9
Vapor Pressure (mm Hg): 1.0 @ 160C (320F)

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Ammonium Chloride involvement in a fire causes decomposition to form hydrogen chloride and ammonia.
Hazardous Polymerization: Will not occur.
Incompatibilities: Concentrated acids, strong bases, silver salts, potassium chlorate, ammonium nitrate, bromine trifluoride and iodine heptafluoride. Ammonium Chloride reacts explosively with potassium chlorate or bromine trifluoride, and violently with bromide pentafluoride, ammonium compounds, nitrates and iodine heptafluoride. Explosive nitrogen trichloride may result from reaction of ammonium chloride and hydrogen cyanide.
Conditions to Avoid: Heat, moisture, incompatibles.

Oral rat LD50 : 1650 mg/kg Investigated as a mutagen.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Toxicity to fish:
LC50 - Cyprinus carpio (Carp) - 209,00 mg/l - 96 h
LC50 - Oncorhynchus mykiss (rainbow trout) - 3,98 mg/l - 96 h
NOEC - Oncorhynchus mykiss (rainbow trout) - 57 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: LC50 - Daphnia magna (Water flea) - 161 mg/l - 48 h
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Environmental Toxicity: Toxic to aquatic life.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Ammonium Chloride in accordance with legal requirements.

DOT (USA) & ADR/RID: Not Regulated
IMDG: Not dangerous goods
IATA: Not dangerous goods

USA:
SARA Section 302 (RQ): CAS# 12125-02-9: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ): None of the chemicals in this product have a TPQ.
SARA Codes: CAS # 12125-02-9: acute, chronic.
Section 313: No chemicals are reportable under Section 313.
Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act: CAS# 12125-02-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.
California No Significant Risk Level: None of the chemicals in this product are listed.

Canada: CAS# 12125-02-9 is listed on Canada's DSL List. This product has a WHMIS classification of

D2B. CAS# 12125-02-9 is listed on Canada's Ingredient Disclosure List.
WHMIS (Canada): This product has a WHMIS classification of D2B.

Disclaimer:
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Our company provides this Ammonium Chloride SDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This Ammonium Chloride MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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