Glycerin SDS MSDS Sheet
Mubychem Limited of USA & India is a pioneer manufacturers suppliers exporters & importers of chemicals including Hydraulic fracturing stimulation & oil well production chemicals, Pharmaceutical excipients, Fragrance & flavor chemicals. Muby Chem Ltd has several manufacturing facilities and toll manufacturers across the globe. We have offices warehouses and representatives in Houston & Midland Texas and Chicago Illinois USA. Our suppliers have accreditations like FDA - GMP-GLP approval, ISO-9001, ISO-22000 HACCP, Kosher & Halal Certification. We offer Commercial Pure Pharmacopoeia Analytical Reagent & Food Grade of Chemicals and do Toll Manufacturing for Oil well drilling fracking fracturing and others. Glycerin Supplier's Specifications
Glycerin SDS MSDS Sheet, Material Safety Data Sheet
Section 1 - Chemical Product and Company Identification
MSDS Name: Glycerin
Synonyms: 1,2,3-Propanetriol; Glycerol, Glycerine, Glyceritol, Glycic Alcohol.Section 2 - Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Signal Words: Warning
Hazard statements:
H316: Causes mild skin irritation
H320: Causes eye irritationPrecautionary statements:
P280: Wear protective gloves/protective clothing/eye protection/face protection
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+ P351+ P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Section 3 - Composition, Information on Ingredients
Chemical Name: Glycerin and Glycerol.
CAS#: 56-81-5Section 4 - First Aid Measures
Always consult a physician after the first aid is given.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flammability: Flammable. Explosive in presence of oxidizing materials.
Flash Point: CLOSED CUP: 160°C (320°F).
Auto Ignition Temperature: 370°C (698°F)
Extinguishing Media: Use Water, dry chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto-ignition or explosion.
NFPA CODE: health: 1; flammability: 1; instability: 0.
Glycerin is incompatible with strong oxidizers.Section 6 - Accidental Release Measures
Spills/Leaks: Use proper personal protective equipment. Restrict unprotected personnel from the area. Remove all ignition sources and ventilate area. Contain the spill with sand or other inert absorbent material, neutralize with sodium bicarbonate or calcium hydroxide, and deposit in a sealed bag or container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Wash area with soap and water. Use water spray to disperse the gas/vapor.Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container of Glycerin tightly closed. Avoid ingestion and inhalation. Do not allow contact with heat. Do not breathe vapors or spray mist.
Storage: Store Glycerin in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store Glycerin protected from heat and incompatible materials.Section 8 - Exposure Controls, Personal Protection
Airborne Exposure Limits:
ACGIH TLV is 10mg/m3.
OSHA PEL is 10 mg/m3 total, 5 mg/m3 respirable.
NIOSH Not established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area of Glycerin.Section 9 - Physical and Chemical Properties
Appearance: Clear Liquid
Odor: Faint odor
Solubility: Miscible in water
Specific Gravity: 1.26g/cm3 @ 20C
pH: 6
% Volatiles by volume @ 21C (70F): NA
Boiling Point: 290 deg C ( 554F)
Melting Point: 17.8C
Molecular Formula: C3H8O3
Molecular Weight: 92.1Section 10 - Stability and Reactivity
Chemical Stability: Glycerin is stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, exposure to heat, spark.
Incompatibilities with Other Materials: Oxidizing agents, strong alkalis and metals.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.Section 11 - Toxicological Information
Acute oral toxicity (LD50): 4090 mg/kg [Mouse] 4 hours.
Acute oral toxicity (LD50): 12600 mg/kg [Rat] 4 hours.
Acute dermal toxicity (LD50): 21900 mg/kg [Rat] 4 hours.
Acute dermal toxicity (LD50): 10000 mg/kg [Rabbit] 4 hours.
Acute toxicity of the mist (LC50): >570 mg/m3 1 hours [Rat].The material is not reported as a carcinogen.
Section 12 - Ecological Information
Environmental Fate: The material will readily biodegrade.
Environmental Toxicity: LC50 (24 hour(s), Goldfish) 5000 mg/l; LC50 (96 Hr.) rainbow trout = 50-67 mg/L; EC50 (24 hour(s), Daphnia magna 500mg/LSection 13 - Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Glycerin and unused contents in accordance with local requirements.
Section 14 - Transport Information
DOT (US)
Not Regulated.IMDG
Not Regulated.IATA
Not Regulated.Section 15 - Regulatory Information
USA FEDERAL
OSHA:
Not Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this material have an RQ.
Section 313
No chemicals are reportable under Section 313.
SARA 311/312 Hazards
Acute Health Hazard Immediate
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 56-81-5 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.Canada
CAS# 56-81-5 is listed on Canada's DSL List.
This product does not WHMIS classification.
CAS# 56-81-5 is not listed on Canada's Ingredient Disclosure List.
WHMIS (Canada): CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). CLASS E: Corrosive liquid.Section 16 - Additional Information
Disclaimer:
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Our company provides this Glycerin SDS information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This Glycerin SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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