Cerium Ceric Ammonium Nitrate Manufacturers, SDS MSDS Sheet

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Ceric Ammonium Nitrate MSDS Sheet, Material Safety Data Sheet Cerium Ammonium Nitrate

Synonyms: CAN, Ammonium Hexanitratocerate (IV), Diammonium Hexanitratocerate, Hexanitrato Ammoniumcerate, Ceric Ammonium Nitrate, Ammonium Cerium Nitrate.
CAS No.: 16774-21-3
Molecular Weight: 548.23
Chemical Formula: (NH4)2Ce(NO3)6

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910

Hazard Statements:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.

Flammability of the Product: Non-flammable but it is an oxidizer.
Products of Combustion: It emits toxic oxides of nitrogen when heated to decomposition.
Fire: Ceric Ammonium Nitrate is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion.
Fire Extinguishing Media: Water spray. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Ceric Ammonium Nitrate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage or contact with combustible substances.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Cerium ammonium nitrate is Orange Red or Orange Yellow crystals or powder or granules.
Odor: Slight.
Solubility: 141g/100ml water @ 25C (77F).
pH: Not available at 10% solution at 25C (77F)
Density: No information found.
Molecular formula: (NH4)2Ce(NO3)6
Molecular weight: 548.23
% Volatiles by volume @ 21C (70F): 0
Boiling Point: > 1600C (> 2912F)
Melting Point: 107C with decomposition for Ceric Ammonium Nitrate.
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

Stability: Cerium Ammonium Nitrate is stable under ordinary conditions of use and storage. Substance will pick up moisture from the air and go into solution if exposed in open containers.
Hazardous Decomposition Products: It emits toxic oxides of nitrogen when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Metal powders and Reducing agents.
Conditions to Avoid: Incompatibles.

Toxicity to Animals: LD50: Not available. LC50: Not available.
Special Remarks on Toxicity to Animals: Not available.
Carcinogenic Effects: Not available.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Chronic Effects on Humans: May cause damage to the following organs: lungs, mucous membranes.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Acute Potential Health Effects:
Skin: Causes skin irritation with possible burning sensation especially if skin is wet or moist.
Eyes: Causes eye irritation with redness and pain.
Inhalation: Causes respiratory tract irritation. Symptoms may include coughing, and shortness of breath.
Ingestion: Ingestion of large doses of nitrates causes gastrointestinal tract irritation with nausea, vomiting, abdominal cramps, diarrhea (possibly bloody, from gastrointestinal hemorrhage). Under some circumstances, when the nitrate is converted by bacteria in the stomach to nitrite, it may also cause methemoglobinemia, cyanosis (a bluish discoloration of the skin due to deficient oxygenation of the blood), convulsions and death. Methemoglobinemia is characterized by dizziness, weakness, fatigue, convulsions (seizures), drowsiness, headache, shortness of breath, cyanosis, rapid heart rate (tachycardia) or slow heart rate (bradycardia), hypotension, chocolate brown colored blood, unconsciousness.

Environmental Fate: No information found.
Environmental Toxicity: The material is not considered as environmental hazard.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

DOT (USA)
UN number: 1477 Class: 5.1 Oxidizing material. Packing group: II
Proper shipping name: Nitrates, inorganic, n.o.s.
Reportable Quantity (RQ):
Marine pollutant: No
Poison Inhalation Hazard: No

IMDG
UN number: 1477 Class: 5.1 Packing group: II EMS-No: F-A, S-Q
Proper shipping name: NITRATES, INORGANIC, N.O.S.
Marine pollutant: No

IATA
UN number: 1477 Class: 5.1 Packing group: II
Proper shipping name: Nitrates, inorganic, n.o.s.

OSHA Hazards: Oxidizer, Toxic by ingestion, Irritant.
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 313: This material contains Ammonium cerium(IV) nitrate (listed as Water Dissociable Nitrate Compounds), 98+%, (CAS# 16774-21-3) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
SARA 311/312 Hazards: Acute Health Hazard.
SARA Codes: CAS # 16774-21-3: immediate, fire.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
California Prop 65: California No Significant Risk Level: None of the chemicals in this product are listed.

Canada - DSL/NDSL
CAS# 16774-21-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of C, D2B.
Canadian Ingredient Disclosure List
CAS# 16774-21-3 is not listed on the Canadian Ingredient Disclosure List.

Disclaimer:
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Our company provides this Cerium Ceric Ammonium Nitrate SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Cerium Ammonium Nitrate MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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