Calcium Nitrite Manufacturers, SDS MSDS Sheet

Mubychem Limited of USA & India is a pioneer manufacturers suppliers exporters & importers of chemicals including Hydraulic fracturing stimulation & oil well production chemicals, Pharmaceutical excipients, Fragrance & flavor chemicals. Muby Chem Ltd has several manufacturing facilities and toll manufacturers across the globe. We have offices warehouses and representatives in Houston & Midland Texas and Chicago Illinois USA.

Our suppliers have accreditations like FDA - GMP-GLP approval, ISO-9001, ISO-22000 HACCP, Kosher & Halal Certification. We offer Commercial Pure Pharmacopoeia Analytical Reagent & Food Grade of Chemicals and do Toll Manufacturing for Oil well drilling fracking fracturing and others.

Synonyms: Calcium Salt of Nitrous Acid, Calcium dinitrite, Daraset.
CAS No.: 13780-06-8
EINECS: EC Number: 237-424-2.
Molecular Weight: 132.09
Chemical Formula: Ca(NO2)2 ( Calcium Nitrite)

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910

Hazard Statements:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H320: Causes eye irritation.
H402: Harmful to aquatic life.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P273: Avoid release to the environment.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.

Emergency Overview
Danger! Strong oxidizer. Contact with other material may cause a fire. Causes eye irritation. May cause skin and respiratory tract irritation. May cause methemoglobinemia.
The primary routes of industrial overexposure for the solution are via inhalation and contact with skin and eyes.

Ingredient: Calcium Nitrite
CAS No.: 13780-06-8
Percent: 94 - 100% Apart from the assay, it has mainly Calcium Nitrate.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.

Flammability of the Product: Non-flammable. However the product supports combustion.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: When heated to decomposition, emits acid fumes.
Fire: Calcium Nitrite is not considered to be a fire hazard though it supports combustion as an oxidizer.
Explosion: Containers may explode in the heat of a fire.
Fire Extinguishing Media: Preferably use water sprat. Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. Calcium Nitrite is a Strong Oxidizer. May decompose explosively when heated or involved in a fire. May accelerate burning if involved in a fire.

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.

Keep Calcium Nitrite in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Calcium Nitrite is white crystals or powder or granules.
Odor: It is odorless.
Solubility: It is freely soluble in water.
pH: Not known.
Density: : 2.26 gm/cc.
Molecular formula: Ca(NO2)2
Molecular weight: 132.09
% Volatiles by volume @ 21C (70F): 0
Boiling Point: Not known.
Melting Point: 390C.
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

Stability: Calcium Nitrite is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic acid fumes when heated to decomposition. Nitrogen oxides (NOx), Calcium oxide are formed.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reactive with reducing agents, organic materials. The product may undergo hazardous decomposition, condensation or polymerization, it may react violently with water to emit toxic gases or it may become self-reactive under conditions of shock or increase in temperature or pressure.
Conditions to Avoid: Incompatibles. Avoid contact with combustible material (paper, wool, oil).

Routes of Entry: Inhalation, Ingestion, Eye Contact.
Toxicity to Animals: LD50 (Oral-Rat) 940 mg/kg
Special Remarks on Toxicity to Animals: Not available.
Carcinogenic Effects: Not known to be carcinogenic.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Chronic Effects on Humans: Overexposure to high concentrations or prolonged exposure can result in damage to respiratory system tissues, convulsions, methemoglobinemia and cyanosis.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Acute Potential Health Effects:
Skin: Causes skin irritation with possible burning sensation especially if skin is wet or moist.
Eyes: Causes eye irritation.
Inhalation: Harmful if inhaled. May cause respiratory tract irritation.
Ingestion: Harmful if swallowed.

Environmental Fate: Based on available information Calcium Nitrite will not biodegrade or bio accumulate.
Environmental Toxicity: The product may be harmful to plants, animals and fish.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

Proper Shipping Name: Nitrites, Inorganic, (Calcium Nitrite)
U.N. No.: 2627
Hazard Class and Packing Group Number: 5.1, PG II
Marine Pollutant: NO

OSHA: Not Listed
US SARA reporting requirements: The components of this product are subject to the reporting requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act, and are listed as follows:
Chemical Name Calcium Nitrite (as Nitrite Compounds, Water Dissociable)
SARA 302 (40 CFR 355, Appendix A) No
SARA 304 (40 CFR Table 302.4) No
SARA 313 (40 CFR 372.65) Yes
US SARA Threshold Planning quantity: There are no specific Threshold Planning Quantities for the components of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg) therefore applies, per 40 CFR 370.20.
US SARA Hazard categories (section 311/312, 40 CFR 370-21): Acute: Yes; Chronic: Yes; Fire: No; Reactive: No; Sudden Release: No
Canadian DSL Inventory: The components of this product are on the DSL Inventory.
Canadian WHMIS Symbols: Class D2B: Materials Causing Other Toxic Effects.

Disclaimer:
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Our company provides this Calcium Nitrite SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Calcium Nitrite MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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