Calcium Nitrate Manufacturers, SDS MSDS Sheet

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Synonyms: Nitric acid, calcium salt, tetrahydrate; Norwegian saltpeter tetrahydrate; Calcium dinitrate tetrahydrate; Lime nitrate tetrahydrate; Nitrocalcite tetrahydrate; Lime saltpeter tetrahydrate.
CAS No.: 13477-34-4
Molecular Weight: 236.15
Chemical Formula: Ca(NO3)2.4H2O (Calcium Nitrate Tetrahydrate)

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910

Hazard Statements:
H272: May intensify fire; oxidizer.
H303 May be harmful if swallowed.
H316 Causes mild skin irritation.
H320: Causes eye irritation.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.

Flammability of the Product: Non-flammable.
Products of Combustion: When heated to decomposition, emits acid fumes.
Fire: Calcium Nitrate Tetrahydrate is not considered to be a fire hazard though it supports combustion as an oxidizer.
Explosion: Containers may explode in the heat of a fire.
Fire Extinguishing Media: Preferably use water sprat. Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. Calcium Nitrate Tetrahydrate is a Strong Oxidizer. May decompose explosively when heated or involved in a fire. May accelerate burning if involved in a fire.

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system.

Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Calcium Nitrate Tetrahydrate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Calcium Nitrate Tetrahydrate is white crystals or flakes or granules.
Odor: It is odorless.
Solubility: It is freely soluble in water, exothermic.
pH: 5.0 - 9 at 10% solution at 25C (77F)
Density: 1.84 g/cm3
Molecular formula: Ca(NO3)2-4H2O
Molecular weight: 236.15
% Volatiles by volume @ 21C (70F): 0
Boiling Point: > 1600C (> 2912F)
Melting Point: 43C for Calcium Nitrate Tetrahydrate.
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.

Stability: Calcium Nitrate Tetrahydrate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic acid fumes when heated to decomposition. Nitrogen oxides (NOx), Calcium oxide are formed.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reactive with reducing agents, organic materials. The product may undergo hazardous decomposition, condensation or polymerization, it may react violently with water to emit toxic gases or it may become self-reactive under conditions of shock or increase in temperature or pressure.
Conditions to Avoid: Incompatibles. Avoid contact with combustible material (paper, wool, oil).

Toxicity to Animals: LD50 [oral, rat]; 3900 mg/kg; LC50 [rat]; N/A; LD50 Dermal [rabbit]; N/A
Carcinogenic Effects: Not available.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Chronic Effects on Humans: The substance is toxic to lungs, mucous membranes.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Chronic Effects on Humans: May affect genetic material.
Special Remarks on other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).

Environmental Fate: Based on available information Calcium Nitrate Tetrahydrate will not biodegrade or bio accumulate.
Environmental Toxicity: The material is not considered as environmental hazard.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

DOT Shipping Name: Calcium Nitrate. Canada TDG: Calcium Nitrate.
DOT Hazard Class: 5.1 Oxidizing Material, pg III. Hazard Class: 5.1, pg III.
Identification Number: UN1454. UN Number: UN1454.

USA:
OSHA Hazards
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA Codes
CAS # 13477-34-4: immediate, fire.
CAS # 10124-37-5: immediate, fire.
Section 313
This material contains Calcium nitrate tetrahydrate (listed as Water Dissociable Nitrate Compounds), >99%, (CAS# 13477-34-4) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR
SARA 311/312 Hazards
Reactivity Hazard
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

Canada - DSL/NDSL
CAS# 10124-37-5 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of C, D2B.
Canadian Ingredient Disclosure List
CAS# 13477-34-4 is not listed on the Canadian Ingredient Disclosure List.
CAS# 10124-37-5 is not listed on the Canadian Ingredient Disclosure List.

Disclaimer:
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Our company provides this Calcium Nitrate Tetrahydrate SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Calcium Nitrate Tetrahydrate MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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