Sodium Metabisulfite Sodium Metabisulphite Manufacturers SDS MSDS Sheet

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Sodium Metabisulfite SDS MSDS Sheet, Sodium Metabisulphite Material Safety Data Sheet

Synonyms: Disulfurous acid, Disodium salt, Fertisilo; Pyrosulfurous acid, disodium salt; Sodium disulfite; Disodium pyrosulfite; Sodium pyrosulfite.
CAS No.: 7681-57-4 Sodium Metabisulfite or Sodium Metabisulphite.
Molecular Weight: 190.11
Chemical Formula: Na2S2O5 (sodium metabisulfite)

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4
Acute toxicity, dermal Category 5
Serious eye damage/eye irritation Category 1

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
EUH031: Contact with acids liberates toxic gas.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash with plenty of water and soap thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Wear protective equipment for hands, eyes, face and respiratory tract.
P270: Do not eat, drink or smoke when using this product.
P301 + P330: IF SWALLOWED: rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313 : If skin irritation occurs: Get medical advice/attention.
P312 : Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container to hazardous or special waste collection point.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Fire: Sodium Metabisulfite is not considered to be a fire hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Do not allow water runoff to enter sewers or waterways.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

Ventilate area of leak or spill. Wear appropriate personal protective equipment.
Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. Cautiously spray residue with plenty of water, providing ventilation to clear sulfur dioxide fumes generated from water contact. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities.

Keep Sodium Metabisulfite in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Releases toxic sulfur dioxide gas when in contact with water, ice. Keep away from acids, water, ice, and oxidizing agents. Use only with appropriate protective equipment. Do not use in unventilated areas such as holds of fishing boats, walk in coolers or confined spaces. Containers of Sodium Metabisulphite may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

Airborne Exposure Limits:
-ACGIH Threshold Limit Value (TLV):
5mg/m3 (TWA) for sodium metabisulfite, A4 Not classifiable as a human carcinogen.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face respirator with an acid gas cartridge may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. (neoprene, polyvinyl chloride).
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

Appearance: Sodium Metabisulfite is white to yellow white crystalline granules.
Odor: Slight odor of sulfur dioxide.
Solubility: Very soluble in water, insoluble in alcohol.
Specific Gravity: 1.48
pH: Aqueous solution is acidic.
Melting Point: 150C (302F)

Stability: Product is normally stable. Sodium Metabisulfite is air and moisture sensitive and releases sulfur dioxide slowly at ambient temperatures. Sodium Metabisulfite will decompose on heating to form sodium sulfate. Contact with moisture (water, wet ice, etc.), will release toxic sulfur dioxide gas.
Hazardous Decomposition Products: Oxides of sulfur and sodium may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Water, acids, alkalis, sodium nitrite, oxidizers, aluminum powder.
Conditions to Avoid: Moisture, heat, flames, ignition sources and incompatibles.

11. Toxicological Information
LD50 Oral - Rat - 1.540 mg/kg
LD50 Dermal - Rat - > 2.000 mg/kg
Investigated as a tumorigen, mutagen and tumorigen reproductive effector.
--------\Cancer Lists\-----------------------------------------------
-------- ------------------------- --NTP Carcinogen-
Ingredient ------------------------- Known Anticipated IARC Category
------------------------------------- -------- ------------- -------------
Sodium Metabisulfite (7681-57-4) No ---- No ---------- 3

Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) - 150 - 220 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 89 mg/l - 24 h
Toxicity to algae: IC50 - Desmodesmus subspicatus (green algae) - 48 mg/l - 72 h
Toxicity to bacteria: Pseudomonas putida - 56 mg/l - 17 h
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.. Dispose of container of Sodium Metabisulfite and unused contents in accordance with legal requirements.

USA:
SARA 302: Sodium Metabisulfite (7681-57-4) No; Sodium Bisulfite (7631-90-5) No
SARA 313: Sodium Metabisulfite (7681-57-4) No; Sodium Bisulfite (7631-90-5) --- No
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
SARA 311/312: Acute: Yes; Chronic: No; Fire: No; Pressure: No; Reactivity: Yes (Mixture / Solid)

Canada WHMIS: CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
Canada DSL: Sodium Metabisulfite (7681-57-4) Yes; Sodium Bisulfite (7631-90-5) Yes
Canada NDSL: Sodium Metabisulfite (7681-57-4) No; Sodium Bisulfite (7631-90-5) No

Disclaimer:
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Our company provides this Sodium metabisulfite metabisulphite SDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This Sodium metabisulfite MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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