Calcium Chloride Anhydrous Manufacturers, SDS MSDS Sheet

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Calcium Chloride BP USP ACS Analytical Reagent Food Grade
Calcium Chloride Anhydrous Fused Dihydrate Hexahydrate Solution IP Grade Manufacturers Specifications & Uses

For MSDS Sheet Click
CaCl2 Anhydrous MSDS Sheet
CaCl2 Fused Dihydrate MSDS Sheet
CaCl2 Hexahydrate Solution MSDS Sheet

Calcium Chloride
Fused, Anhydrous, Lumps, Powder, Crystals, Dihydrate, Hexahydrate, Tablets, Pellets, Solution, Brine
Also IP BP Ph. Eur. USP ACS AR LR FCC Food Grades

Calcium Chloride Anhydrous Calcium Chloride Dihydrate

Calcium Chloride SDS MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Synonyms: Calcium Dichloride; Calcium Di Chloride
CAS No.: 10043-52-4
Molecular Weight: 110.98
Chemical Formula: CaCl2 (Calcium Chloride Anhydrous)

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910

Irritant

Signal Words: Caution

Hazard statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/ attention.

Emergency Overview
WARNING! CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. HARMFUL IF SWALLOWED OR INHALED. 

3. Composition/Information on Ingredients

Ingredient: Calcium Chloride Anhydrous
CAS No.: 10043-52-4
Percent: 93 - 100%

4. First Aid Measures

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Oral ingestion may cause serum acidosis.

5. Fire Fighting Measures

Fire: Calcium Chloride is not considered to be a fire hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.

6. Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.

7. Handling and Storage

Keep Calcium Chloride in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Moist calcium chloride and concentrated solutions can corrode steel. When exposed to the atmosphere, calcium chloride will absorb water and form a solution.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards.

9. Physical and Chemical Properties

Appearance: Calcium Chloride is white or gray-white granules.
Odor: It is odorless.
Solubility: It is freely soluble in water, exothermic.
Density: Calcium Chloride has specific gravity of 2.15
pH: 8 - 9 Aqueous solution of Calcium Chloride
% Volatiles by volume @ 21C (70F): 0
Boiling Point: > 1600C (> 2912F)
Melting Point: 772C (1422F)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.

10. Stability and Reactivity

Stability: Calcium Chloride is stable under ordinary conditions of use and storage. Substance will pick up moisture from the air and go into solution if exposed in open containers.
Hazardous Decomposition Products: It emits toxic chlorine fumes when heated to decomposition. Calcium Chloride may form hydrogen chloride in presence of sulfuric or phosphoric acids or with water at elevated temperatures.
Hazardous Polymerization: Will not occur.
Incompatibilities: Methyl vinyl ether, water, zinc, bromine trifluoride, mixtures of lime and boric acid, barium chloride, and 2-furan percarboxylic acid. Metals will slowly corrode in aqueous calcium chloride solutions. Aluminum (and alloys) and yellow brass will be attacked by calcium chloride.
Conditions to Avoid: Incompatibles.

11. Toxicological Information

Oral rat LD50: 1000 mg/kg. Investigated as a tumorigen and mutagen.

12. Ecological Information

Environmental Fate: Based on available information for Calcium Chloride anhydrous, this material will not biodegrade or bio accumulate.
Environmental Toxicity: The LC50/96-hour values for fish are over 100 mg/l.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Calcium Chloride and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Calcium Chloride is not regulated.

15. Regulatory Information

SARA 311/312:  Acute: Yes; Chronic: No; Fire: No; Pressure: No
Reactivity: No  (Pure / Solid)
California Proposition 65: Not listed.

WHMIS (Canada): CLASS D-2B: Material causing other toxic effects (TOXIC).

16. Other Information

Disclaimer:
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Our company provides this Calcium Chloride SDS information sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Calcium Chloride MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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