Mubychem Limited of USA is a pioneer manufacturers suppliers exporters & importers of chemicals including Hydraulic fracturing stimulation & oil well production chemicals, Pharmaceutical excipients, Fragrance & flavor chemicals. Muby Chem Ltd has several manufacturing facilities and toll manufacturers across the globe. We have offices warehouses and representatives in Houston & Midland Texas and Chicago Illinois USA.
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BHA Butylated Hydroxyanisole Manufacturers, MSDS Sheet

Butylated Hydroxyanisole
BHA Food grade
Butylated Hydroxyanisole

Apart from Butylated hydroxyanisole Manufacturers we also manufacture Butylated hydroxytoluene, and Tertiary or Tert Butylhydroquinone the main antioxidants for oils and fats.

Typical Analysis & Butylated hydroxyanisole specifications:

Butylated hydroxyanisole is a white to slightly yellow waxy flakes with characteristic odor.
It is freely soluble in alcohol, propylene glycol.  It is insoluble in water.

Test ---------------- Result - Specification
Melting Point ------- 62.6C -- 48C to 63C
Residue on ignition - 0.018% - 0.05% max
Arsenic ------------- <1ppm -- 3ppm max
Assay --------------- 99.06% - 98.5% min of C11H16O2

Packing will be 25-50 kg or 50 lbs in bags or drums or as desired by the buyer.

Salient Features of BHA

The most effective antioxidant, imparting excellent stability for an array of food products, fats, shortenings, vitamins, pet foods, cosmetics pharmaceutical products and packaging material.
BHA, reduces the oxidative deterioration of edible oils and fats, loss of flavor, colour and nutritive value of foods.
BHA, THE BETTER ANTIOXIDANT : BHA normally is a mixture of 2 isomers, 2 tert butyl and 3 tert butyl isomers 3 tert butyl isomer has better antioxidant property.
White free flowing crystalline Flakes.
Stable to heat and mildly alkaline conditions.
20% colorless solution in propylene glycol remains colorless even when heated at 1940F for 1hr.
BHA SYNERGISTIC EFFECT : BHA gives greater synergistic effect with TBHQ, BHT and propyl gallate than that which might be expected from contribution of each individual antioxidant.

 

BHA Butylated Hydroxyanisole MSDS Sheet, Material Safety Data Sheet

1. Product Identification

CAS No.: 25013-16-5
Molecular Weight: 180.25
Chemical Formula: C11H16O2

2. Composition/Information on Ingredients

Ingredient: Butylated Hydroxyanisole, BHA
CAS No.: 25013-16-5
Percent: 97 - 100%
Hazardous: Yes

3. Hazards Identification

OSHA Hazards:
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
HMIS Classification
Health hazard: 2
Flammability: 1
Reactivity: 0
Personal Protection: E
NFPA Rating
Health hazard: 2
Fire: 1
Reactivity Hazard: 0
Protective Equip: Goggles, Lab Coat.

Emergency Overview

Warning! Possible cancer hazard. May cause cancer based on animal data. Risk of cancer depends on duration and level of exposure. Harmful if swallowed. Causes eye, skin, and respiratory tract irritation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Target Organs: Blood, liver, respiratory system, eyes, skin.

Potential Health Effects
Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation (lung irritant). Slightly hazardous in case of ingestion.
Eye: Causes eye irritation.
Skin: Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion: Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation: Causes severe respiratory tract irritation. May be harmful if inhaled.
Chronic: Possible cancer hazard based on tests with laboratory animals. Prolonged or repeated skin contact may cause dermatitis. Chronic exposure may cause liver damage. Adverse reproductive effects have been reported in animals. Laboratory experiments have resulted in mutagenic effects. Chronic exposure may cause blood effects. Animal studies have reported the development of tumors.

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Flammability of the Product: May be combustible at high temperature..
Auto-Ignition Temperature: Not available.
Flash Points: 156C.
Flammable Limits: Not available.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Fire: Flamable in the presence of open flame.
Explosion: Slightly explosive in presence of heat.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures o.r when moistened under fire conditions, it may produce toxic or irritating fumes. On decomposition it may emit hydrogen chloride. Containers may explode on heating

6. Accidental Release Measures

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

7. Handling and Storage

Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep Butylated Hydroxyanisole, BHA in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: Not established.
Ventilation System
: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Butylated Hydroxyanisole, BHA is a white to off-white waxy solid.
Odor: It has faint typical odor.
Solubility: It is immiscible in water.
pH: NA
Density: 1.05 g/mL at 20C (68F)
Molecular Weight:
180.2
Molecular Formula: C11H16O2
% Volatiles by volume @ 21C (70F): -
Boiling Point: 264-270C
Melting Point: 48 - 55 deg C
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity

Stability: Butylated Hydroxyanisole, BHA is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, reducing agents metals and acids.
Conditions to Avoid
: Incompatibles and moisture.
Phenols are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides.
Avoid use of aluminium, copper and brass alloys in storage and process equipment.
Heat is generated by the acid-base reaction between phenols and bases.
Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature), these reactions generate heat.
Phenols are nitrated very rapidly, even by dilute nitric acid.
Nitrated phenols often explode when heated. Many of them form metal salts that tend toward detonation by rather mild shock.
Segregate from oleum, nitric acid and chlorosulfonic acid.

11. Toxicological Information

Acute toxicity
Toxic if swallowed. Chronic exposure may cause damage to a variety of body organs. Harmful if inhaled.

Toxicity data
ORL-RAT LD50 > 2000 mg kg-1
ORL-MAM LD50 1100 mg kg-1

Routes of Entry: Inhalation. Ingestion. Skin
Special Remarks on Toxicity to Animals: Not available.
Carcinogenic Effects: Classified 2B (Possible for human.) by IARC. Classified 2 (Some evidence.) by NTP.
Mutagenic Effects: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: blood, liver, upper respiratory tract, skin.
Teratogenic Effects: Teratogenic effects have occurred in experimental animals.
Developmental Toxicity: Adverse reproductive effects have occurred in experimental animals.
May affect genetic material (mutagenic). May cause adverse reproductive effects based on animal test data. May cause cancer.

12. Ecological Information

Environmental Fate: Not available.
Environmental Toxicity: Not known.
BOD5 and COD: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

US DOT Classification:
Not Regulated

Canada TDG Classification:
Not Regulated

IATA
Not Regulated

15. Regulatory Information

OSHA Hazards
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
No chemicals are reportable under Section 313.
SARA 311/312 Hazards
Component CAS # 25013-16-5.
Fire Hazard: No
Reactivity Hazard: No
Pressure Hazard: No
Immediate Health Hazard: Acute
Chronic Health Hazard: Delayed
Massachusetts Right To Know Components
Listed
Pennsylvania Right To Know Components
Listed
New Jersey Right To Know Components
Listed
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: BHA
California prop. 65 (no significant risk level): BHA: 4 mg/day (value)
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: BHA
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
EINECS: EC Number: 246-563-8
Hazard Symbols:
XN N
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 40 Limited evidence of a carcinogenic effect.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 29 Do not empty into drains.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S 61 Avoid release to the environment.
WGK (Water Danger/Protection)
CAS# 25013-16-5: No information available.
Canada - DSL/NDSL
CAS# 7447-39-4 is listed on Canada's DSL List.
Canada - WHMIS
CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
Canadian Ingredient Disclosure List
CAS# 25013-16-5 is listed on the Canadian Ingredient Disclosure List.
TSCA
CAS# 25013-16-5 is listed on the TSCA Inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
DSCL (EEC):
R22- Harmful if swallowed.
R36/37/38- Irritating to eyes respiratory system and skin.
R40- Limited Evidence of Carcinogenic Effect
S36/37- Wear suitable protective clothing and gloves.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles.

Australian Hazchem Code: -
Poison Schedule: -

16. Other Information

Disclaimer:
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Our company provides this BHA Butylated Hydroxyanisole, MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This Butylated Hydroxyanisole, BHA MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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BHA Butylated Hydroxyanisole manufacturers:

Muby Chem Ltd.
Toll manufacturing & Warehouse at Houston Beasley & Midland, Texas, USA
USA, Canada, Mexico Customers may e-mail: usa@mubygroup.com
Call 1-844-682-9243

Europe Africa Asia India Mumbai e-mail: info@mubygroup.com
Call +91-22-23774610

Mubychem Ltd. Manufacturers Suppliers USA

Exporters Importers between USA Canada UAE Europe South Africa Tanzania Kenya Uganda Egypt Nigeria Turkey Mexico Brazil Argentina Chile Dubai China India etc.
 26 June, 2015. Copyright and Usual Disclaimer is Applicable.

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Butylated Hydroxyanisole Manufacturers

Butylated Hydroxyanisole Manufacturers

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